In the past, laminated glass was usually installed in the windshield, with side and rear windows being tempered only.
The difference is that tempered glass is per-stressed so that when it cracks, it shatters into many tiny and dull pieces. Laminated is the same thing, but with layers of plastic sandwiched with layers of tempered glass. Laminated glass will still shatter, but will be held together by the plastic layers.
In an emergency, small improvised, or purpose built tools meant to shatter tempered glass will be useless if the glass is laminated.
In the states? Gun.
Rest of the world? Crowbar?
Not a handgun if you want to be able to exit through the opening. Under water? Not sure a shotgun will even be helpful unless you fire at all corners to break it up more thoroughly.
18 pounder cannon, as the founding father’s intended.