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SalamanderMA to Chemistry · 1 年前

The anti-aromatic dianion and aromatic tetraanion of [18]annulene - Nature Chemistry

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The anti-aromatic dianion and aromatic tetraanion of [18]annulene - Nature Chemistry

www.nature.com

SalamanderMA to Chemistry · 1 年前
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A previous investigation of the anti-aromatic dianion of [18]annulene concluded that it consists of a mixture of two isomers. Now it has been shown that this dianion exists as a single isomer, with a different geometry from neutral [18]annulene, and that it can be reduced further to an aromatic tetraanion.
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