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SalamanderMA to Spectroscopy · 2 years ago

Ultrafast electronic relaxation pathways of the molecular photoswitch quadricyclane - Nature Chemistry

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Ultrafast electronic relaxation pathways of the molecular photoswitch quadricyclane - Nature Chemistry

www.nature.com

SalamanderMA to Spectroscopy · 2 years ago
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Light-induced ultrafast switching between the molecular isomers norbornadiene and quadricyclane can reversibly store and release a substantial amount of chemical energy. Two competing pathways have now been identified by which electronically excited quadricyclane molecules relax to the electronic ground state, facilitating interconversion between the two isomers on different timescales.
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